1. At 120∘C 120^{\circ} \mathrm{C} 120∘C temperature and 1.5 atm 1.5 \mathrm{~atm} 1.5 atm, pressure the below reaction is at equilibrium state-
AB5( g)⇌AB3( g)+B2( g) \mathrm{AB}_{5}(\mathrm{~g}) \rightleftharpoons \mathrm{AB}_{3}(\mathrm{~g})+\mathrm{B}_{2}(\mathrm{~g}) AB5( g)⇌AB3( g)+B2( g)
Here A A A and B B B are the elements of 3 rd period and AB5 A B_{5} AB5 is dissociated 30% 30 \% 30%.
What is common ion effect?
Explain that AlCl3 \mathrm{AlCl}_{3} AlCl3 forms dimer.
Explain the hybridization of AB3 \mathrm{AB}_{3} AB3.
If pressure of the reaction in the stem is changed to 0.143 atm 0.143 \mathrm{~atm} 0.143 atm then the degree of dissociation will be increased-Explain mathematically.
2.
Write down the Aufbau principle.
Why is the 2 d 2 \mathrm{~d} 2 d orbital not possible? Explain.
Explain with causes the structural differences of the hydrides of C C C and D D D.
Showed graph of the elements in the stem is not linear-explain with cause.
3.
What is called electron affinity?
Why the value of Ke \mathrm{K}_{\mathrm{e}} Ke is not infinite? Explain.
Calculate the wavelength of radiated ray in the stem.
'E shell does not contain more than 32 electrons'? Explain with quantum number.
4. A student wrote the following two electronic configurations for A A A and B B B :
A(19)=1s22s22p63s23p63d1 A(19)=1 s^{2} 2 s^{2} 2 p^{6} 3 s^{2} 3 p^{6} 3 d^{1} A(19)=1s22s22p63s23p63d1 (according to Aufbau rule)
What is called safe food?
All d-block elements are not transition elementExplain.
Verify Paulie's exclusion principle for e1 e_{1} e1 and e2. e_{2}. e2.
Explain with proper reason whether two electronic configurations written by the student are correct.
5.
What is called Law of Mass Action?
Why the range of pH \mathrm{pH} pH scale from ' 0 to 14'?
Explain the possibility of formation of compound AC5 \mathrm{AC}_{5} AC5 and BC5 \mathrm{BC}_{5} BC5.
Analyze the utility of similarity of bond angles though the hybridization of the hydride of A A A and B are same.