1. (i) Fe2++MnO4+H+⟶Fe3++Mn2++H2O \mathrm{Fe}^{2+}+\mathrm{MnO}_{4}+\mathrm{H}^{+} \longrightarrow \mathrm{Fe}^{3+}+\mathrm{Mn}^{2+}+\mathrm{H}_{2} \mathrm{O} Fe2++MnO4+H+⟶Fe3++Mn2++H2O
(ii) I2+S2O32⟶S4O62+I− \mathrm{I}_{2}+\mathrm{S}_{2} \mathrm{O}_{3}^{2} \longrightarrow \mathrm{S}_{4} \mathrm{O}_{6}^{2}+\mathrm{I}^{-} I2+S2O32⟶S4O62+I−
(iii) HCOOH+Na2CO3⟶HCOONa+H2O+CO2 \mathrm{HCOOH}+\mathrm{Na}_{2} \mathrm{CO}_{3} \longrightarrow \mathrm{HCOONa}+\mathrm{H}_{2} \mathrm{O}+\mathrm{CO}_{2} HCOOH+Na2CO3⟶HCOONa+H2O+CO2
Define ETP.
Why is NaCl \mathrm{NaCl} NaCl used in leather tanning?
Identify the oxidizing and reducing agents of reaction-(i) and explain reason.
Are the reactions (ii) and (iii) same in nature? Analyze.
Industry
Components
No-1
Air, natural gas
No-2
Leather, lime,
Na2 Cr2 O−7, H2 SO4Na_{2\ }Cr_{2\ }O-7,\ H_2\ SO_4Na2 Cr2 O−7, H2 SO4
No-3
Scrap ship
Write down the Beer-Lambert's law.
Is recemic mixture optically active? Explain.
Describe the production of Iron from the components of Industry-3.
Which one plays more role in environmental pollution between the Industry-1 and Industry- 2? Analyse.
3.
Write down Faraday's first law.
Why is gypsum added in cement?
Describe how to prepare an aromatic compound from 'A'.
Which one will be more acidic between ' A \mathrm{A} A ' and 'B'? Analyse.
Solution- 1
15 mL 0.02M H2C2O415\ mL\ 0.02M\ H_2C_2O_415 mL 0.02M H2C2O4
Solution- 2
5 mL 10% NaOH
Indicator
Range of pH change
A
3.1-4.4
8.3-10.0
Define peptide bond.
Why is anhydrous AlCl3AlCl_3AlCl3 used in Friedel-Craft reaction?
Calculate the concentration of solution-2 in ppm unit.
Which indicator of stem is suitable for the titration of solution-1 by the solution-2? Analyze.
5.
What is called COD?
What is the Cullet used in the manufacturing of glass?
Write down the principle of manufacturing an important fertilizer from ' B \mathrm{B} B ' in the stem.
Can ' A \mathrm{A} A ' of stem show the silver mirror test? Analyse.