1. Stem: 0.105 molPCl5,0.045 molCl2 0.105 \mathrm{~mol} \mathrm{PCl}_{5}, 0.045 \mathrm{~mol} \mathrm{Cl}_{2} 0.105 molPCl5,0.045 molCl2 and 0.045 mol 0.045 \mathrm{~mol} 0.045 mol PCl3 \mathrm{PCl}_{3} PCl3 are mixed in flask of volume 0.5 L 0.5 \mathrm{~L} 0.5 L. At 25∘C 25^{\circ} \mathrm{C} 25∘C temperature KC \mathrm{K}_{\mathrm{C}} KC of the following reaction is 4.2×10−2 4.2 \times 10^{-2} 4.2×10−2 mol/L \mathrm{mol} / \mathrm{L} mol/L
PCl5( g)⇌PCl3+Cl2( g) \mathrm{PCl}_{5}(\mathrm{~g}) \rightleftharpoons \mathrm{PCl}_{3}+\mathrm{Cl}_{2}(\mathrm{~g}) PCl5( g)⇌PCl3+Cl2( g)
What is chemical bonding?
Explain the co-ordination bond in NH4+ \mathrm{NH}_{4}^{+} NH4+ion.
At equilibrium the concentration of PCl5 \mathrm{PCl}_{5} PCl5 is 0.2065 mol/L 0.2065 \mathrm{~mol} / \mathrm{L} 0.2065 mol/L. Calculate the concentration of other two components.
To which side the stem reaction will be proceded? Analyze.
Element
Electron Configuration
D
1 s1 1 \mathrm{~s}^{1} 1 s1
X
He[2 s22p4] \mathrm{He}\left[2 \mathrm{~s}^{2} 2 \mathrm{p}^{4}\right] He[2 s22p4]
G
He[2 s22p5] \mathrm{He}\left[2 \mathrm{~s}^{2} 2 \mathrm{p}^{5}\right] He[2 s22p5]
E
Ne[3 s1] \mathrm{Ne}\left[3 \mathrm{~s}^{1}\right] Ne[3 s1]
[Here D,X,G,E \mathrm{D}, \mathrm{X}, \mathrm{G}, \mathrm{E} D,X,G,E are not traditional symbols of elements]
What is electronegativity of element?
Why 614C { }_{6}^{14} \mathrm{C} 614C and 816O { }_{8}^{16} \mathrm{O} 816O are the isotone isotone of each other? Explain.
Which one between D2X \mathrm{D}_{2} \mathrm{X} D2X and DG \mathrm{DG} DG has the higher melting point? Expalin.
Which one between the compound E2X \mathrm{E}_{2} \mathrm{X} E2X and EG \mathrm{EG} EG is more covalent in nature? Analyze.
3. (i) N2( g)+3H2( g)⇌2NH3( g)+ \mathrm{N}_{2}(\mathrm{~g})+3 \mathrm{H}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NH}_{3}(\mathrm{~g})+ N2( g)+3H2( g)⇌2NH3( g)+ heat
(ii) N2( g)+O2( g)⇌2NO(g)−43.0kCl \mathrm{N}_{2}(\mathrm{~g})+\mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{NO}(\mathrm{g})-43.0 \mathrm{kCl} N2( g)+O2( g)⇌2NO(g)−43.0kCl
What is antimicrobial?
Explain the role of salt in the food preservation.
Calculate the KP \mathrm{K}_{\mathrm{P}} KP of the reaction (i) when 3.85% 3.85 \% 3.85% of NH3 \mathrm{NH}_{3} NH3 is obtained in the equilibrium at 400∘C 400^{\circ} \mathrm{C} 400∘C and 10 atm 10 \mathrm{~atm} 10 atm presure.
Analyze the conditions for increasing the product of the reactions (i) and (ii).
4.
What is transition element?
How is hydrogen spectrum formed? Explain.
Calculate the pH \mathrm{pH} pH of the solution in pot-X.
Which one between D \mathrm{D} D and E \mathrm{E} E will act as buffer solution? Analyze it mathematically.
5. Follow the hydrogen model below:
State the law of mass action.
What is meant by acidity is of Al2O3 \mathrm{Al}_{2} \mathrm{O}_{3} Al2O3 6? Explain.
Determine the largest wavelength of line spectrum when electrons are transferred to ' B \mathrm{B} B ' energy leve.
Energy difference between 'A' and ' C \mathrm{C} C ' energy level is 1.93×10−18 J 1.93 \times 10^{-18} \mathrm{~J} 1.93×10−18 J. Explain mathematically whether the radiated light will be visible or not.